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Synthesis of novel magneto-hybrid polyoxometalate composite membrane with simultaneous photocatalyticself-cleaning and antifouling functionalities

《化学科学与工程前沿（英文）》 2023年 第17卷 第10期   页码 1450-1459 doi: 10.1007/s11705-023-2310-3

摘要： Membrane technology is ideal for removing aqueous humic acid, but humic acid deposits cause membrane fouling, a significant challenge that limits its application. Herein, this work proposed an alternative approach to the controllably magnetically induced magneto-hybrid polyoxometalate (magneto-HPOM) nanocomposite migration toward the polyethersulfone (PES) membrane surface under a magnetic field to enhance the self-cleaning and antifouling functionalities of the membrane. Before incorporating magneto-HPOM nanocomposite into the PES casting solution, functionalized magnetite nanoparticles (F-MNP) were first coated with HPOM photocatalyst to fabricate a magneto-HPOM-PES membrane. It was shown that the apparent impacts of this novel magneto-HPOM-PES membrane on the hydrophilic behavior and photocatalytic properties of the magneto-HPOM nanocomposite improve the hydrophilicity, separation performance, antifouling and self-cleaning properties of the membrane compared with neat PES membrane. Furthermore, after exposure to ultraviolet light, the magneto-HPOM-PES membrane can be recovered after three cycles with a flux recovery ratio of 107.95%, 100.06%, and 95.56%, which is attributed to the temporal super hydrophilicity effect. Meanwhile, the magneto-HPOM-PES membrane could efficiently maintain 100% humic acid rejection for the first and second cycles and 99.81% for the third cycle. This study revealed a novel approach to fabricating membranes with high antifouling and self-cleaning properties for water treatment.

关键词： magneto-hybrid polyoxometalate nanocomposite     composite membrane     antifouling     self-cleaning     magnetic and photocatalytic responsiveness    

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G-CNTs/PVDF mixed matrix membranes with improved antifouling properties and filtration performance

Xiaoyan Guo, Chunyu Li, Chenghao Li, Tingting Wei, Lin Tong, Huaiqi Shao, Qixing Zhou, Lan Wang, Yuan Liao

《环境科学与工程前沿（英文）》 2019年 第13卷 第6期 doi: 10.1007/s11783-019-1165-9

摘要：

A novel nanocomposite OMWCNT-A-GO was synthesized by conjugating OMWCNT and GO.

The P-OMWCNT-A-GO membrane was fabricated by non-solvent induced phase inversion.

The P-OMWCNT-A-GO exhibits the best water flux, BSA rejection and flux recovery.

It should be due to the enhanced membrane pore size, porosity and hydrophilicity.

关键词： carbon nanotubes     graphene oxide     mixed matrix membrane     nanohybrid     antifouling membrane     membrane hydrophilicity    

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Electro-assisted CNTs/ceramic flat sheet ultrafiltration membrane for enhanced antifouling and separation

Shuo Wei, Lei Du, Shuo Chen, Hongtao Yu, Xie Quan

《环境科学与工程前沿（英文）》 2021年 第15卷 第1期 doi: 10.1007/s11783-020-1303-4

摘要： Abstract • A stable and electroconductive CNTs/ceramic membrane was fabricated. • The membrane with the electro-assistance exhibited optimal fouling mitigation. • The removal efficiency was improved by the -2.0 V electro-assistance. • Electro-assisted filtration is energy-saving than that of commercial membrane. Ultrafiltration is employed as an important process for water treatment and reuse, which is of great significance to alleviate the shortage of water resources. However, it suffers from severe membrane fouling and the trade-off between selectivity and permeability. In this work, a CNTs/ceramic flat sheet ultrafiltration membrane coupled with electro-assistance was developed for improving the antifouling and separation performance. The CNTs/ceramic flat sheet membrane was fabricated by coating cross-linked CNTs on ceramic membrane, featuring a good electroconductivity of 764.75 S/m. In the filtration of natural water, the permeate flux of the membrane with the cell voltage of -2.0 V was 1.8 times higher than that of the membrane without electro-assistance and 5.7-fold greater than that of the PVDF commercial membrane. Benefiting from the electro-assistance, the removal efficiency of the typical antibiotics was improved by 50%. Furthermore, the electro-assisted membrane filtration process showed 70% reduction in energy consumption compared with the filtration process of the commercial membrane. This work offers a feasible approach for membrane fouling mitigation and effluent quality improvement and suggests that the electro-assisted CNTs/ceramic membrane filtration process has great potential in the application of water treatment.

关键词： Ultrafiltration     Electro-assistance     CNTs     Membrane fouling mitigation    

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effect of poly(ethylene-co-vinyl alcohol) molecular weight and vinyl alcohol content on morphology, antifouling, and permeation properties of polysulfone ultrafiltration membrane: thermodynamic and formation hydrodynamic

《化学科学与工程前沿（英文）》 2023年 第17卷 第10期   页码 1484-1502 doi: 10.1007/s11705-023-2331-y

摘要： Various hydrophilic poly(ethylene-co-vinyl alcohol) (EVOH) were used herein to precisely control the structure and hydrodynamic properties of polysulfone (PSF) membranes. Particularly, to prepare pristine PSF and PSF/EVOH blends with increasing vinyl alcohol (VOH: 73%, 68%, 56%), the non-solvent-induced phase separation (NIPS) technique was used. Polyethylene glycol was used as a compatibilizer and as a porogen in N,N-dimethylacetamide. Rheological and ultrasonic separation kinetic measurements were also carried out to develop an ultrafiltration membrane mechanism. The extracted membrane properties and filtration capabilities were systematically compared to the proposed mechanism. Accordingly, the addition of EVOH led to an increase in the rheology of the dopes. The resulting membranes exhibited a microporous structure, while the finger-like structures became more evident with increasing VOH content. The PSF/EVOH behavior was changed from immediate to delayed segregation due to a change in the hydrodynamic kinetics. Interestingly, the PSF/EVOH32 membranes showed high hydrophilicity and achieved a pure water permeability of 264 L·m–2·h–1·bar–1, which was higher than that of pure PSF membranes (171 L·m–2·h–1·bar–1). In addition, PSF/EVOH32 rejected bovine serum albumin at a high rate (> 90%) and achieved a significant restoration of permeability. Finally, from the thermodynamic and hydrodynamic results, valuable insights into the selection of hydrophilic copolymers were provided to tailor the membrane structure while improving both the permeability and antifouling performance.

关键词： polysulfone     blend modification     ultrafiltration membrane     formation hydrodynamics     poly(ethylene-co-vinyl alcohol) copolymer    

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Nonpolar cross-stacked super-aligned carbon nanotube membrane for efficient wastewater treatment

《环境科学与工程前沿（英文）》 2023年 第17卷 第3期 doi: 10.1007/s11783-023-1630-3

摘要：

● A novel nonpolar super-aligned carbon nanotube (SACNT) membrane was prepared.

关键词： Membrane fouling     Wastewater     Membrane separation     Antifouling     Aligned carbon nanotube    

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An antifouling catechol/chitosan-modified polyvinylidene fluoride membrane for sustainable oil-in-water

Shanshan Zhao, Zhu Tao, Liwei Chen, Muqiao Han, Bin Zhao, Xuelin Tian, Liang Wang, Fangang Meng

《环境科学与工程前沿（英文）》 2021年 第15卷 第4期 doi: 10.1007/s11783-020-1355-5

摘要： Abstract • Underwater superoleophobic membrane was fabricated by deposition of catechol/chitosan. • The membrane had ultrahigh pure water flux and was stable under harsh pH conditions. • The membrane exhibited remarkable antifouling property in O/W emulsion separation. • The hydration layer on the membrane surface prevented oil droplets adhesion. Low-pressure membrane filtrations are considered as effective technologies for sustainable oil/water separation. However, conventional membranes usually suffer from severe pore clogging and surface fouling, and thus, novel membranes with superior wettability and antifouling features are urgently required. Herein, we report a facile green approach for the development of an underwater superoleophobic microfiltration membrane via one-step oxidant-induced ultrafast co-deposition of naturally available catechol/chitosan on a porous polyvinylidene fluoride (PVDF) substrate. Membrane morphology and surface chemistry were studied using a series of characterization techniques. The as-prepared membrane retained the original pore structure due to the ultrathin and uniform catechol/chitosan coating. It exhibited ultrahigh pure water permeability and robust chemical stability under harsh pH conditions. Moreover, the catechol/chitosan hydrophilic coating on the membrane surface acting as an energetic barrier for oil droplets could minimize oil adhesion on the surface, which endowed the membrane with remarkable antifouling property and reusability in a cyclic oil-in-water (O/W) emulsion separation. The modified membrane exhibited a competitive flux of ~428 L/(m2·h·bar) after three filtration cycles, which was 70% higher than that of the pristine PVDF membrane. These results suggest that the novel underwater superoleophobic membrane can potentially be used for sustainable O/W emulsions separation, and the proposed green facile modification approach can also be applied to other water-remediation materials considering its low cost and simplicity.

关键词： Antifouling     Catechol/chitosan co-deposition     Oil-in-water emulsions separation     Underwater superoleophobic    

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Surface modification techniques of membranes to improve their antifouling characteristics: recent advancements

《化学科学与工程前沿（英文）》 2023年 第17卷 第12期   页码 1837-1865 doi: 10.1007/s11705-023-2347-3

摘要： Surface modification techniques of membranes to improve their antifouling characteristics: recent advancements and developments

关键词： Surface modification techniques    

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Membrane fouling control by ultrasound in an anaerobic membrane bioreactor

SUI Pengzhe, WEN Xianghua, HUANG Xia

《环境科学与工程前沿（英文）》 2007年 第1卷 第3期   页码 362-367 doi: 10.1007/s11783-007-0062-9

摘要： In this study, ultrasound was used to control the membrane fouling online in an anaerobic membrane bioreactor (AMBR). Short-term running experiments were carried out under different operating conditions to explore feasible ultrasonic parameters. The experimental results indicated that when the crossflow velocity was more than 1.0 m/s, membrane fouling could be controlled effectively only by hydrodynamic methods without ultrasound. When ultrasound was applied, an ultrasonic power range of 60–150 W was suitable for the membrane fouling control in the experimental system. The experimental results showed that the membrane fouling was controlled so well that membrane filtration resistance (Σ) could stay at 5 × 10 m for more than a week with the crossflow velocity of 0.75 m/s, which equaled the effect of crossflow velocity of more than 1.0 m/s without ultrasound.

关键词： membrane filtration     filtration resistance     different     feasible ultrasonic     anaerobic membrane    

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Novel membrane separation technologies and membrane processes

Yanying Wei, Gongping Liu, Jianquan Luo, Libo Li, Zhi Xu

《化学科学与工程前沿（英文）》 2021年 第15卷 第4期   页码 717-719 doi: 10.1007/s11705-021-2053-y

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A critical review on thermodynamic mechanisms of membrane fouling in membrane-based water treatment process

《环境科学与工程前沿（英文）》 2023年 第17卷 第10期 doi: 10.1007/s11783-023-1729-6

摘要：

● Fundamentals of membrane fouling are comprehensively reviewed.

关键词： Membrane fouling     Thermodynamic mechanism     XDLVO theory     Flory-Huggins theory     Fouling migration    

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A review on membrane distillation in process engineering: design and exergy equations, materials and

《化学科学与工程前沿（英文）》 2022年 第16卷 第5期   页码 592-613 doi: 10.1007/s11705-021-2105-3

摘要： One of the problems that most afflicts humanity is the lack of clean water. Water stress, which is the pressure on the quantity and quality of water resources, exists in many places throughout the World. Desalination represents a valid solution to the scarcity of fresh water and several technologies are already well applied and successful (such as reverse osmosis), producing about 100 million m3·d−1 of fresh water. Further advances in the field of desalination can be provided by innovative processes such as membrane distillation. The latter is of particular interest for the treatment of waste currents from conventional desalination processes (for example the retentate of reverse osmosis) as it allows to desalt highly concentrated currents as it is not limited by concentration polarization phenomena. New perspectives have enhanced research activities and allowed a deeper understanding of mass and heat transport phenomena, membrane wetting, polarization phenomena and have encouraged the use of materials particularly suitable for membrane distillation applications. This work summarizes recent developments in the field of membrane distillation, studies for module length optimization, commercial membrane modules developed, recent patents and advancement of membrane material.

关键词： membrane distillation     recent developments     heat and mass transfer     wetting     membrane material    

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Pilot plants of membrane technology in industry: Challenges and key learnings

Colin A. Scholes

《化学科学与工程前沿（英文）》 2020年 第14卷 第3期   页码 305-316 doi: 10.1007/s11705-019-1860-x

摘要： Membrane technology holds great potential in gas separation applications, especially carbon dioxide capture from industrial processes. To achieve this potential, the outputs from global research endeavours into membrane technologies must be trialled in industrial processes, which requires membrane-based pilot plants. These pilot plants are critical to the commercialization of membrane technology, be it as gas separation membranes or membrane gas-solvent contactors, as failure at the pilot plant level may delay the development of the technology for decades. Here, the author reports on his experience of operating membrane-based pilot plants for gas separation and contactor configurations as part of three industrial carbon capture initiatives: the Mulgrave project, H3 project and Vales Point project. Specifically, the challenges of developing and operating membrane pilot plants are presented, as well as the key learnings on how to successfully manage membrane pilot plants to achieve desired performance outcomes. The purpose is to assist membrane technologists in the carbon capture field to achieve successful outcomes for their technology innovations.

关键词： membrane gas separation     membrane contactors     carbon capture     pilot plants     key learnings    

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Membrane bioreactors for hospital wastewater treatment: recent advancements in membranes and processes

《化学科学与工程前沿（英文）》 2022年 第16卷 第5期   页码 634-660 doi: 10.1007/s11705-021-2107-1

摘要： Discharged hospital wastewater contains various pathogenic microorganisms, antibiotic groups, toxic organic compounds, radioactive elements, and ionic pollutants. These contaminants harm the environment and human health causing the spread of disease. Thus, effective treatment of hospital wastewater is an urgent task for sustainable development. Membranes, with controllable porous and nonporous structures, have been rapidly developed for molecular separations. In particular, membrane bioreactor (MBR) technology demonstrated high removal efficiency toward organic compounds and low waste sludge production. To further enhance the separation efficiency and achieve material recovery from hospital waste streams, novel concepts of MBRs and their applications are rapidly evolved through hybridizing novel membranes (non hydrophilic ultrafiltration/microfiltration) into the MBR units (hybrid MBRs) or the MBR as a pretreatment step and integrating other membrane processes as subsequent secondary purification step (integrated MBR-membrane systems). However, there is a lack of reviews on the latest advancement in MBR technologies for hospital wastewater treatment, and analysis on its major challenges and future trends. This review started with an overview of main pollutants in common hospital wastewater, followed by an understanding on the key performance indicators/criteria in MBR membranes (i.e., solute selectivity) and processes (e.g., fouling). Then, an in-depth analysis was provided into the recent development of hybrid MBR and integrated MBR-membrane system concepts, and applications correlated with wastewater sources, with a particular focus on hospital wastewaters. It is anticipated that this review will shed light on the knowledge gaps in the field, highlighting the potential contribution of hybrid MBRs and integrated MBR-membrane systems toward global epidemic prevention.

关键词： membrane technology     membrane bioreactor     hospital wastewater     hybrid MBR     integrated MBR-membrane system    

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Highly hydrophobic oil−water separation membrane: reutilization of waste reverse osmosis membrane

《化学科学与工程前沿（英文）》 2023年 第17卷 第10期   页码 1606-1615 doi: 10.1007/s11705-022-2200-0

摘要： The increasing applications of seawater desalination technology have led to the wide usage of polyamide reverse osmosis membranes, resulting in a large number of wasted reverse osmosis membranes. In this work, the base nonwoven layer of the wasted reverse osmosis membrane was successfully modified into the hydrophobic membrane via surface deposition strategy including TiO2 and 1H,1H,2H,2H-perfluorooctyltrichlorosilane (PFOTS), respectively. Various techniques were applied to characterize the obtained membranes, which were then used to separate the oil–water system. The optimally modified membrane displayed good hydrophobicity with a contact angle of 135.2° ± 0.3°, and its oil–water separation performance was as high as 97.8%. After 20 recycle tests, the oil–water separation performance remained more than 96%, which was attributed to the film adhesion of the anchored TiO2 and PFOTS layer on the surface. This work might provide a new avenue for recycling the wasted reverse osmosis membrane used in oily wastewater purification.

关键词： oil–water separation     wasted reverse osmosis membrane     hydrophobic modification    

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Aggravation of membrane fouling and methane leakage by a three-phase separator in an external anaerobicceramic membrane bioreactor

Chao Pang, Chunhua He, Zhenhu Hu, Shoujun Yuan, Wei Wang

《环境科学与工程前沿（英文）》 2019年 第13卷 第4期 doi: 10.1007/s11783-019-1131-6

摘要：

The existence of three-phase separator did not affect COD removal in the EAnCMBR.

The existence of three-phase separator aggravated methane leakage of EAnCMBR.

The existence of three-phase separator aggravated membrane fouling rate of EAnCMBR.

Start-up of EAnCMBR equipped three-phase separator was slightly delayed.

关键词： Anaerobic membrane bioreactor     Three-phase separator     Membrane fouling     Methane leakage     Sludge property    

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标题 作者 时间 类型 操作

Synthesis of novel magneto-hybrid polyoxometalate composite membrane with simultaneous photocatalyticself-cleaning and antifouling functionalities

期刊论文

G-CNTs/PVDF mixed matrix membranes with improved antifouling properties and filtration performance

Xiaoyan Guo, Chunyu Li, Chenghao Li, Tingting Wei, Lin Tong, Huaiqi Shao, Qixing Zhou, Lan Wang, Yuan Liao

期刊论文

Electro-assisted CNTs/ceramic flat sheet ultrafiltration membrane for enhanced antifouling and separation

Shuo Wei, Lei Du, Shuo Chen, Hongtao Yu, Xie Quan

期刊论文

effect of poly(ethylene-co-vinyl alcohol) molecular weight and vinyl alcohol content on morphology, antifouling, and permeation properties of polysulfone ultrafiltration membrane: thermodynamic and formation hydrodynamic

期刊论文

Nonpolar cross-stacked super-aligned carbon nanotube membrane for efficient wastewater treatment

期刊论文

An antifouling catechol/chitosan-modified polyvinylidene fluoride membrane for sustainable oil-in-water

Shanshan Zhao, Zhu Tao, Liwei Chen, Muqiao Han, Bin Zhao, Xuelin Tian, Liang Wang, Fangang Meng

期刊论文

Surface modification techniques of membranes to improve their antifouling characteristics: recent advancements

期刊论文

Membrane fouling control by ultrasound in an anaerobic membrane bioreactor

SUI Pengzhe, WEN Xianghua, HUANG Xia

期刊论文

Novel membrane separation technologies and membrane processes

Yanying Wei, Gongping Liu, Jianquan Luo, Libo Li, Zhi Xu

期刊论文

A critical review on thermodynamic mechanisms of membrane fouling in membrane-based water treatment process

期刊论文

A review on membrane distillation in process engineering: design and exergy equations, materials and

期刊论文

Pilot plants of membrane technology in industry: Challenges and key learnings

Colin A. Scholes

期刊论文

Membrane bioreactors for hospital wastewater treatment: recent advancements in membranes and processes

期刊论文

Highly hydrophobic oil−water separation membrane: reutilization of waste reverse osmosis membrane

期刊论文

Aggravation of membrane fouling and methane leakage by a three-phase separator in an external anaerobicceramic membrane bioreactor

Chao Pang, Chunhua He, Zhenhu Hu, Shoujun Yuan, Wei Wang

期刊论文